Regioselective synthesis of the tricyclic core of lateriflorone.
نویسندگان
چکیده
An efficient synthetic approach to the tricyclic core 8 of lateriflorone is described. Essential to the synthesis was the implementation of a biomimetic tandem Claisen/Diels-Alder reaction that produced the desired tricyclic scaffold as a single isomer. A rationalization of the excellent regio and stereoselectivity of this transformation is also proposed. [reaction: see text]
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ورودعنوان ژورنال:
- Organic letters
دوره 5 9 شماره
صفحات -
تاریخ انتشار 2003